4 fires of heat treatment: quenching, tempering, normalizing and annealing

Heat treatment of metal materials includes normalizing, annealing, tempering and quenching. Among them, annealing and normalizing are mainly used for preparatory heat treatment, and are only used as final heat treatment when the performance requirements of the workpiece are not high.
The purpose of quenching is to obtain martensitic organization, improve the performance of metal materials. Tempering is mainly to reduce or eliminate quenching stresses, to prevent deformation or cracking, while obtaining the required mechanical properties.
I. Quenching
1. What is called quenching: steel quenching is the steel heated to the critical temperature Ac3 (sub-eutectic steel) or Ac1 (over-eutectic steel) above temperature, insulation for a period of time, so that all or part of the austenitization, and then faster than the critical cooling rate of the cooling rate of fast cold to Ms (or Ms near the isothermal) for the transformation of martensite (or bainite) heat treatment process. Usually also aluminum alloys, copper alloys, titanium alloys, tempered glass and other materials solution treatment or heat treatment process with rapid cooling process called quenching.
2. The purpose of quenching: to improve the mechanical properties of metal materials or parts. For example: to improve the hardness and wear resistance of tools, bearings, etc., to improve the elastic limit of the spring, to improve the overall mechanical properties of shaft parts. Improve the material properties or chemical properties of some special steel. For example, improve the corrosion resistance of stainless steel, increase the permanent magnetism of magnetic steel.
Quenching and cooling, in addition to the need for reasonable selection of quenching medium, but also the correct quenching method, commonly used quenching methods, mainly single-liquid quenching, dual-liquid quenching, graded quenching, isothermal quenching, local quenching and so on.
3. metal workpiece in the quenching characteristics: ① obtained martensite, bainite, residual austenite and other unbalanced (i.e., unstable) organization. ② the existence of large internal stress. ③ mechanical properties can not meet the requirements. Therefore, steel workpiece quenching generally after tempering
Second, tempering
1. what is called tempering: tempering is the quenched metal material or parts heated to a certain temperature, holding time, in a certain way cooling heat treatment process, tempering is a quenching operation immediately after the quenching, usually is also the last process of heat treatment of the workpiece, and thus the quenching and tempering of the joint process known as the final treatment.
2. The main purpose of quenching and tempering is: to reduce internal stress and reduce brittleness, quenched parts there is a great deal of stress and brittleness, such as the absence of timely tempering tends to produce deformation or even cracking.
Adjust the mechanical properties of the workpiece, workpiece quenching, high hardness, brittleness, in order to meet the different performance requirements of various workpieces, can be adjusted by tempering, hardness, strength, plasticity and toughness.
Stabilize the size of the workpiece. Through the tempering can make the metallurgical organization tends to stabilize, in order to ensure that no further deformation in the future use of the process.
Improve the cutting performance of certain alloy steels.
3. The role of tempering is to: ① improve the stability of the organization, so that the workpiece in the use of the process no longer occurs in the organization of the transformation, so that the workpiece geometry and performance to maintain stability.
② eliminate internal stresses, in order to improve the performance of the workpiece and stabilize the geometry of the workpiece.
③ adjust the mechanical properties of steel to meet the requirements of use.

Tempering has these effects, because when the temperature rises, the atomic activity ability to enhance the steel of iron, carbon and other alloying elements of the atoms can be faster diffusion, atomic rearrangement and combination, so that the unstable imbalance of the organization is gradually transformed into a stable equilibrium organization. The elimination of internal stress is also related to the reduction of metal strength at elevated temperatures. Generally when steel is tempered, hardness and strength decrease and plasticity increases. The higher the tempering temperature, the greater the change in these mechanical properties. Some alloy steel with high alloy element content, when tempered at a certain temperature range, will precipitate some fine-grained metal compounds, so that the strength and hardness rise. This phenomenon is called secondary hardening.
Tempering requirements: workpieces for different purposes should be tempered at different temperatures to meet the requirements in use.
① Cutting tools, bearings, carburized quenched parts, surface quenched parts are usually tempered at a low temperature below 250℃. Low-temperature tempering after the hardness does not change much, the internal stress is reduced, the toughness is slightly improved.
② springs tempered at 350-500 ℃ under medium temperature, can obtain high elasticity and necessary toughness.
③ medium-carbon structural steel parts usually made in 500 ~ 600 ℃ for high-temperature tempering, in order to obtain the appropriate strength and toughness of a good match.

Steel is often made more brittle when tempered at about 300°C, a phenomenon known as Type I tempering embrittlement. Generally should not be tempered in this temperature range. Some medium-carbon alloy structural steel tempered at high temperatures, if slowly cooled to room temperature, but also easy to become brittle. This phenomenon is known as Type II temper embrittlement. The addition of molybdenum to the steel, or cooling in oil or water during tempering, can prevent Type II temper embrittlement. The second type of temper brittleness of steel reheating to the original tempering temperature, you can eliminate this brittleness. In production, often according to the requirements of the workpiece properties. According to the different heating temperatures, the tempering is divided into low-temperature tempering, medium-temperature tempering, and high-temperature tempering. Quenching and subsequent high-temperature tempering combined heat treatment process known as tempering, that is, in a high degree of strength at the same time, but also good plastic toughness.
(1) low-temperature tempering: 150-250 ℃ , M back, reduce internal stress and brittleness, improve the plastic toughness, high hardness and wear resistance. Used in the production of gauges, cutting tools and rolling bearings.
(2) medium temperature tempering: 350-500 ℃, T back, with high elasticity, a certain degree of plasticity and hardness. Used for making springs, forging molds, etc.
3 High temperature tempering: 500-650 ℃ , S back, with good overall mechanical properties. For the production of gears, crankshafts, etc.
Third, normalizing
1. What is normalizing: normalizing is a heat treatment to improve the toughness of steel. The steel component is heated to Ac3 temperature above 30 ~ 50 ℃, after holding a period of time out of the air-cooled. The main feature is that the cooling rate is faster than annealing and lower than quenching, normalizing can be slightly faster cooling in the crystalline grain refinement of steel, not only to get satisfactory strength, but also can significantly improve the toughness (AKV value), reduce the tendency to cracking components. Some low alloy hot rolled steel plate, low alloy steel forgings and castings by normalizing treatment, the comprehensive mechanical properties of the material can be greatly improved, but also improved cutting performance.
2. The purpose and use of normalizing: ① eutectic steel, normalizing to eliminate casting, forging, welded parts of the overheating coarse crystalline organization and Wei's organization, rolled material in the banded organization; refinement of grain; and can be used as a quenching before the pre-heat treatment.
② eutectic steel, normalizing can eliminate the network of secondary carburization, and pearlite refinement, not only to improve the mechanical properties, but also conducive to the subsequent spherical annealing.
③ low carbon deep-drawn thin steel plate, normalizing can eliminate free carburization of grain boundaries to improve its deep-drawn properties.
④ low carbon steel and low carbon low alloy steel, the use of normalizing, you can get more fine flake pearlitic organization, so that the hardness increased to HB140-190, to avoid cutting the "sticky knife" phenomenon, improve the cutting processability. For medium carbon steel, in both available normalizing and annealing occasions, with normalizing is more economical and convenient.
⑤ For ordinary medium-carbon structural steel, in the mechanical properties required for the occasion is not high, can be used instead of quenching quenching and high-temperature tempering, not only easy to operate, but also to make the organization of steel and dimensional stability.
⑥ High-temperature normalizing (Ac3 above 150 ~ 200 ℃) due to the high temperature diffusion rate is higher, can reduce the composition of castings and forgings segregation. High-temperature normalizing after the coarse grains can be refined by the subsequent second lower temperature normalizing.
(vii) for some of the turbine and boiler used in low and medium carbon alloy steel, often using normalizing to obtain the bainite organization, and then by high temperature tempering, used for 400 ~ 550 ℃ has good creep resistance.
⑧ In addition to steel parts and steel, normalizing is also widely used in ductile iron heat treatment, so that it obtains pearlite matrix, improve the strength of ductile iron.
Because of the characteristics of normalizing air cooling, and therefore the ambient air temperature, stacking mode, airflow and workpiece size on the organization and properties after normalizing have an impact. The normalized organization can also be used as a classification method for alloy steels. Usually according to the diameter of 25 mm specimen heated to 900 ℃, air-cooled organization, the alloy steel is divided into pearlite steel, bainitic steel, martensitic steel and austenitic steel.
Four, annealing
1. what is annealing: annealing is the metal slowly heated to a certain temperature, maintained for a sufficient period of time, and then cooled at a suitable rate of a metal heat treatment process. Annealing heat treatment is divided into complete annealing, incomplete annealing and stress relief annealing. The mechanical properties of annealed materials can be detected by tensile tests and also by hardness tests. Many steel materials are supplied in annealed heat-treated condition, steel hardness testing can be used Rockwell hardness tester, test HRB hardness, for thinner steel plates, steel strips, and thin-walled steel tubes, you can use the surface Rockwell hardness tester, test HRT hardness.

2. The purpose of annealing: ① to improve or eliminate the steel in the casting, forging, rolling and welding process caused by a variety of organizational defects, as well as residual stress, to prevent the workpiece deformation, cracking.
② soften the workpiece for cutting.
③ refine the grain, improve the organization to improve the mechanical properties of the workpiece.
④ For the final heat treatment (quenching, tempering) to prepare the organization.
3. commonly used annealing process: ① complete annealing. Used to refine the medium and low carbon steel by casting, forging and welding after the mechanical properties of poor coarse superheated organization. The workpiece will be heated to ferrite all transformed into austenite temperature above 30 ~ 50 ℃, hold for a period of time, and then slowly cooled with the furnace, the austenite in the cooling process again, you can make the organization of the steel fine.
② spheroidal annealing. Used to reduce the high hardness of tool steel and bearing steel after forging. The workpiece will be heated to the steel began to form austenite temperature above 20 ~ 40 ℃, after holding slowly cooled, in the cooling process of pearlite in the lamellar carburite into spherical, thus reducing the hardness.
③ Isothermal annealing. Used to reduce the high hardness of certain alloy structural steel with high nickel and chromium content for cutting. Generally first cooled to the austenite at a faster rate to the temperature of the most unstable, insulation for an appropriate period of time, the austenite transformed into tosite or sostenite, hardness can be reduced.
④ recrystallization annealing. Used to eliminate metal wire, sheet in the cold drawing, cold rolling process of hardening phenomenon (hardness increases, plasticity decreases). Heating temperature for the steel generally began to form austenite temperature below 50 ~ 150 ℃, only so that the elimination of work hardening effect of softening the metal.
⑤ Graphitization annealing. ⑤ Graphitization annealing. This is used to transform cast iron containing a large amount of carburization into malleable cast iron with good plasticity. Process operation is the casting is heated to about 950 ℃, insulation for a certain period of time after appropriate cooling, so that the decomposition of carburite to form a flocculent graphite.
⑥ diffusion annealing. Used to make the chemical composition of alloy castings uniform, improve its performance. Method is not melting under the premise of the casting heated to the highest possible temperature, and a long period of heat preservation, to be a variety of elements in the alloy diffusion tends to be uniformly distributed after slow cooling.
(7) stress relief annealing. Used to eliminate the internal stress of steel castings and weldments. For iron and steel products begin to form austenite after heating the temperature below 100 to 200 ℃, insulation and cooling in the air, you can eliminate internal stress.